From The Collaborative International Dictionary of English v.0.48 :
Pentagon \Pen"ta*gon\, n. [Gr. penta`gwnon; penta- (see Penta-) + gwni`a angle: cf. L. pentagonium, F. pentagone.] (Geom.) A plane figure having five angles, and, consequently, five sides; any figure having five angles. [1913 Webster] Regular pentagon, a pentagon in which the angles are all equal, and the sides all equal. [1913 Webster]From WordNet (r) 3.0 (2006) :
Pentagon n 1: a government building with five sides that serves as the headquarters of the United States Department of Defense 2: the United States military establishment 3: a five-sided polygon